a compound has a chemical composition of 47% carbon, 6% hydrogen, and 47% oxygen. what is the empirical formula? luoa

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Answer 1

Main Answer:The empirical formula is CH₂O.

Supporting Question and Answer:

How can the empirical formula of a compound be determined based on its chemical composition?

The empirical formula of a compound can be determined by finding the simplest whole-number ratio of the elements present in the compound. To calculate the empirical formula, the percentage composition of each element is converted to grams, then the grams are converted to moles. Finally, the moles of each element are divided by the smallest number of moles to obtain the simplest whole-number ratio.

Body of the Solution: To determine the empirical formula of a compound based on its chemical composition, we need to find the simplest whole-number ratio of the elements present.

Given:

Carbon: 47%

Hydrogen: 6%

Oxygen: 47%

To simplify the percentages, we can assume we have 100 grams of the compound. This means we have:

Carbon: 47 grams

Hydrogen: 6 grams

Oxygen: 47 grams

Next, we need to find the moles of each element. To do this, we divide the mass of each element by its molar mass.

The molar mass of carbon (C) is approximately 12.01 g/mol. The molar mass of hydrogen (H) is approximately 1.01 g/mol. The molar mass of oxygen (O) is approximately 16.00 g/mol.

Now, let's calculate the moles of each element:

Moles of carbon = 47 g C / 12.01 g/mol ≈ 3.916 mol C

Moles of hydrogen = 6 g H / 1.01 g/mol ≈ 5.941 mol H

Moles of oxygen = 47 g O / 16.00 g/mol ≈ 2.938 mol O

To find the simplest whole-number ratio of these moles, we divide each value by the smallest number of moles (in this case, 2.938).

Moles of carbon: 3.916 mol C / 2.938 mol ≈ 1.333 ≈ 4/3 Moles of hydrogen: 5.941 mol H / 2.938 mol ≈ 2.023 ≈ 2

Moles of oxygen: 2.938 mol O / 2.938 mol = 1

Since we need to express the empirical formula with whole numbers, we round the mole ratios to the nearest whole number.

Therefore, the empirical formula of the compound is CH₂O.

Final Answer:Hence, the empirical formula of the compound is CH₂O.

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Answer 2

The empirical formula is CH₂O.

How can the empirical formula of a compound be determined based on its chemical composition?

The empirical formula of a compound can be determined by finding the simplest whole-number ratio of the elements present in the compound. To calculate the empirical formula, the percentage composition of each element is converted to grams, then the grams are converted to moles. Finally, the moles of each element are divided by the smallest number of moles to obtain the simplest whole-number ratio.

To determine the empirical formula of a compound based on its chemical composition, we need to find the simplest whole-number ratio of the elements present.

Given:

Carbon: 47%

Hydrogen: 6%

Oxygen: 47%

To simplify the percentages, we can assume we have 100 grams of the compound. This means we have:

Carbon: 47 grams

Hydrogen: 6 grams

Oxygen: 47 grams

Next, we need to find the moles of each element. To do this, we divide the mass of each element by its molar mass.

The molar mass of carbon (C) is approximately 12.01 g/mol. The molar mass of hydrogen (H) is approximately 1.01 g/mol. The molar mass of oxygen (O) is approximately 16.00 g/mol.

Now, let's calculate the moles of each element:

Moles of carbon = 47 g C / 12.01 g/mol ≈ 3.916 mol C

Moles of hydrogen = 6 g H / 1.01 g/mol ≈ 5.941 mol H

Moles of oxygen = 47 g O / 16.00 g/mol ≈ 2.938 mol O

To find the simplest whole-number ratio of these moles, we divide each value by the smallest number of moles (in this case, 2.938).

Moles of carbon: 3.916 mol C / 2.938 mol ≈ 1.333 ≈ 4/3 Moles of hydrogen: 5.941 mol H / 2.938 mol ≈ 2.023 ≈ 2

Moles of oxygen: 2.938 mol O / 2.938 mol = 1

Since we need to express the empirical formula with whole numbers, we round the mole ratios to the nearest whole number.

Therefore, the empirical formula of the compound is CH₂O.

Hence, the empirical formula of the compound is CH₂O.

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Related Questions

A sample of nitrogen occupies 11.2 liters un- der a pressure of 580 torr at 32°C. What vol- ume would it occupy at 32°C if the pressure were increased to 8 10 torr? Answer in units of I..

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Using Boyle's Law, the new volume is V2 = (11.2 L * 580 torr) / 810 torr ≈ 8.0 L.

Boyle's Law states that the pressure and volume of a gas sample are inversely proportional, as long as the temperature and the amount of gas remain constant.

In this case, the nitrogen sample occupies 11.2 liters at a pressure of 580 torr at 32°C.

To determine the volume it would occupy when the pressure is increased to 810 torr, we use the formula: V1 * P1 = V2 * P2.

By plugging in the given values, we have (11.2 L * 580 torr) / 810 torr ≈ 8.0 L.

Therefore, the nitrogen sample would occupy approximately 8.0 liters at 810 torr pressure and 32°C.

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The volume would be 3.9 L.

We can use the combined gas law to solve this problem, which states that the product of pressure and volume is directly proportional to the product of temperature and the number of moles of gas, assuming constant pressure and temperature:

[tex](P1V1) / (T1) = (P2V2) / (T2)[/tex]

where P1, V1, and T1 are the initial pressure, volume, and temperature, respectively, and P2 and V2 are the final pressure and volume, respectively.

Substituting the given values, we get:

[tex](580 torr)(11.2 L) / (305 K) = (810 torr)(V2) / (305 K)[/tex]

Solving for V2, we get [tex]V2 = (580 torr)(11.2 L)(810 torr) / (305 K)(305 K) = 3.9 L.[/tex]

Therefore, the volume of nitrogen would be 3.9 L if the pressure were increased to 810 torr at 32°C.

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what is the atom economy for the following reactions for the production of hydrogen? which has the greatest atom economy?

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The reaction with the greatest atom economy is reaction (A), which produces hydrogen by the hydrolysis of cellulose. It has an atom economy of 0.6667. This means that 66.67% of the atoms present in the reactants are incorporated into the desired product, hydrogen gas.

Determine the greatest atom economy?

The atom economy for the reactions is as follows:

(A) 6C₆H₁₀O₅ + 7H₂O ⟶ 12H₂ + 6CO₂

Atom economy = (2 × 12) / (6 × (12 + 2 × 1)) = 0.6667

(B) CH₄ + H₂O ⟶ CO + 3H₂

Atom economy = (2 + 3) / (12 + 2 × 1) = 0.4167

(C) CO + H₂O ⟶ CO₂ + H₂

Atom economy = (2 + 2) / (12 + 2 × 1) = 0.3333

(D) Zn + 2HCl ⟶ ZnCl₂ + H₂

Atom economy = 2 / (65 + 2 × 1) = 0.0294

In reaction (B), methane is reacted with water to produce hydrogen and carbon monoxide. The atom economy is 0.4167, indicating that 41.67% of the atoms in the reactants are utilized to form the desired product.

Reaction (C) involves the water-gas shift reaction, converting carbon monoxide and water to carbon dioxide and hydrogen. It has an atom economy of 0.3333, meaning that only 33.33% of the atoms in the reactants contribute to the formation of the desired product.

Reaction (D) is the reaction of zinc with hydrochloric acid to produce zinc chloride and hydrogen gas. It has the lowest atom economy of 0.0294, indicating that only a small fraction of the reactant atoms are utilized to form the desired product.

Therefore, Reaction (A) has the highest atom economy of 0.6667, meaning that 66.67% of the reactant atoms contribute to the production of hydrogen gas through cellulose hydrolysis.

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Comple question here:
What is the atom economy for the following reactions for the production of hydrogen? Which has the greatest atom economy?

(A) 6H 10O 5+7H 2O⟶12H 2+6CO 2

(B) CH 4+H 2O⟶CO+3H2

(C) CO+H 2 O⟶CO 2 +H 2

(D) Zn+2HCl⟶ZnCl 2+H 2

The strongest intermolecular interactions between carbon disulfide CS2 molecules arise from. a) London dispersion forces b) hydrogen bonding c) disulfulfide linkages d) dipole-dipole forces e) ion-dipole interactions

Answers

The strongest intermolecular interactions between carbon disulfide (CS2) molecules arise from a) London dispersion forces. This is because CS2 is a nonpolar molecule, and there is no hydrogen bonding, disulfide linkages, dipole-dipole forces, or ion-dipole interactions present.

The strongest intermolecular interactions between carbon disulfide (CS2) molecules arise from London dispersion forces. These forces are also known as van der Waals forces and are the result of temporary dipoles that form due to the movement of electrons in the molecules. While other types of intermolecular interactions, such as dipole-dipole forces and hydrogen bonding, can also occur, they are generally weaker than London dispersion forces for nonpolar molecules like CS2.

Disulfide linkages and ion-dipole interactions are not relevant in this case as they involve different types of chemical bonding or interactions with charged particles.

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the special feature that determines the family name and chemical reactivity of the organic compound it is found in is called a(n)

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The special feature that determines the family name and chemical reactivity of the organic compound it is found in is called a functional group.

a functional group is a specific atom or group of atoms that is responsible for the characteristic chemical properties of a particular organic compound. Different functional groups give different organic compounds their unique names and reactivity patterns. For example, the presence of a carbonyl functional group (-C=O) in a compound would give it the family name of a ketone and make it more reactive towards nucleophiles.

The special feature that determines the family name and chemical reactivity of the organic compound it is found in is called a functional group.a functional group is a specific group of atoms within a molecule that is responsible for the characteristic chemical reactions of that molecule. The presence and arrangement of these functional groups in a compound help in identifying its class and predicting its chemical behavior.

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use the common tangent construction to determine the activity of pb in systems with the following compositions at 200 ◦c. please give a numerical value for activity.

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Without the specific phase diagram and compositions, it's impossible to provide a numerical value for the activity of Pb for the tangent.

To determine the activity of Pb in systems with given compositions at 200°C using the common tangent construction, follow these steps:

1. Obtain a phase diagram: First, find a Pb-rich phase diagram that includes temperature (T) and composition (X) axes. Make sure the diagram has data for 200°C.

2. Locate the compositions: Identify the compositions given in the question on the phase diagram. For example, if you are given compositions X1 and X2, find those points on the diagram.

3. Draw the common tangent: Draw a tangent line that touches both of the curves corresponding to the compositions X1 and X2 at 200°C. This common tangent line represents the equilibrium state between the two phases at the given temperature.

4. Identify the point of tangency: Locate the point where the tangent line touches the curve for the composition X1. This point represents the equilibrium composition of Pb in that phase.

5. Determine the activity of Pb: Based on the equilibrium composition at the point of tangency, calculate the activity of Pb using the given activity-composition relationship or activity coefficient model (e.g., Raoult's Law or Henry's Law).

Without the specific phase diagram and compositions, it's impossible to provide a numerical value for the activity of Pb. However, these steps should guide you in solving the problem using the common tangent construction method.


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Trace amounts of oxygen gas can be "scrubbed" from gases using the following reaction: 4 Cr2+(aq) + O2(g) + 4 H+(aq)-4 Cr3+(aq) + 2 H2O(l) Which of the following statements is true regarding this reaction? A. O2 (g) is reduced B. Cr2+(aq) is the oxidizing agent. C. O2(g) is the reducing agent. D. Electrons are transferred from 02 to Cr2-

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In the reaction 4 Cr²⁺(aq) + O₂(g) + 4 H⁺(aq) → 4 Cr³⁺(aq) + 2 H₂O(l), trace amounts of oxygen gas are removed from the mixture. This reaction involves redox processes, where oxidation and reduction occur simultaneously. The correct options are A and B.

A. O₂ (g) is reduced: This statement is true. In the reaction, the oxygen gas (O₂) gains electrons, changing its oxidation state from 0 to -2 (in H₂O). Gaining electrons is the process of reduction.

B. Cr²⁺(aq) is the oxidizing agent: This statement is also true. The oxidizing agent is the substance that causes the reduction of another species. In this case, Cr²⁺ causes the reduction of O₂ by accepting electrons and undergoing a change in its oxidation state from +2 to +3.

C. O₂(g) is the reducing agent: This statement is false. The reducing agent is the substance that causes the oxidation of another species. In this reaction, O₂ is reduced, not the reducing agent. The reducing agent is Cr²⁺, as it loses electrons and causes the oxidation of other species.

D. Electrons are transferred from O₂ to Cr²⁺: This statement is false. Electrons are transferred from Cr²⁺ to O₂. Cr²⁺ loses electrons and gets oxidized to Cr³⁺, while O₂ gains electrons and gets reduced to form H₂O.

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a rigid tank with volume 1 m^3 contains a mixture of helium and water vapor at 90 c and 150 kpa. the mole fraction of helium is 0.9. model this mixture as an ideal gas mixture. the gas constant for helium (on a mass basis) is 2077 j/kg-k and the gas constant for water (also on a mass basis) is 461.5 j/kg-k. what is the mole fraction of water vapor in the tank?

Answers

The mole fraction of the water vapor in tank, given that the tank the mole fraction of helium is 0.9, is 0.1

How do i determine the mole fraction of water vapor in the tank?

The following data were obtained from the question:

Volume of tank (V) = 1 m³Temperature (T) = 90 °CPressure (P) = 150 KPaMole fraction of helium = 0.9Mole fraction of water vapor =?

The mole fraction of water vapor in the tank can be obtain as follow:

Mole fraction of helium + Mole fraction of water vapor = 1

0.9 + Mole fraction of water vapor = 1

Collect like terms

Mole fraction of water vapor = 1 - 0.9

Mole fraction of water vapor = 0.1

Thus, from the above calculation, we can conclude that the mole fraction of water vapor is 0.1

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how many moles of nh4cl must be dissolved in 1.50 l of 0.60 m nh3 in order to prepare a buffer of ph 9.46? kb =1.8 x 10-5 for nh3 report answer in moles to 2 places after the decimal.

Answers

To dissolve [tex]NH_{4}Cl[/tex]  in 1.50 L of 0.60 M [tex]NH_{3}[/tex]  solution for preparing a buffer of pH 9.46 is 0.407 moles.

To prepare a buffer of pH 9.46 using [tex]NH_{3}[/tex] and [tex]NH_{4}Cl[/tex], we need to calculate the required amount of [tex]NH_{4}Cl[/tex] to be added to the [tex]NH_{3}[/tex] solution. The pH of the buffer is determined by the equilibrium between [tex]NH_{3}[/tex] and  ions. The pKa of [tex]NH_{4}+[/tex] is 9.25, so the pH of the buffer can be calculated using the Henderson-Hasselbalch equation:

pH = pKa + log([[tex]NH_{3}[/tex]]/[[tex]NH_{4}+[/tex]])

Rearranging the equation, we get:

[[tex]NH_{3}[/tex]]/[[tex]NH_{4}+[/tex]] = [tex]10^{pH - pKa}[/tex]

Substituting the given values, we get:

[[tex]NH_{3}[/tex]]/[[tex]NH_{4}+[/tex]] =[tex]10^{9.46 - 9.25}[/tex] = 2.21

We know that the initial concentration of [tex]NH_{3}[/tex] is 0.60 M, so we can calculate the concentration of [tex]NH_{4}+[/tex] as follows:

[[tex]NH_{4}+[/tex]] = [[tex]NH_{3}[/tex]]/2.21 = 0.60/2.21 = 0.271 M

Now, we need to calculate the amount of [tex]NH_{4}Cl[/tex] to be added to the solution. The reaction between [tex]NH_{4}Cl[/tex] and [tex]NH_{3}[/tex] is as follows:

[tex]NH_{4}Cl[/tex] + [tex]NH_{3}[/tex] → [tex]NH_{4}+[/tex] + [tex]Cl-[/tex]

Since [tex]NH_{4}+[/tex] is required for the buffer, we need to add enough [tex]NH_{4}Cl[/tex] to provide the required concentration of [tex]NH_{4}+[/tex]. The amount of [tex]NH_{4}Cl[/tex] required can be calculated using the formula:

moles of [tex]NH_{4}Cl[/tex] = volume of [tex]NH_{3}[/tex] solution (L) × concentration of [tex]NH_{4}+[/tex] (M)

Substituting the values, we get:

moles of [tex]NH_{4}Cl[/tex] = 1.50 L × 0.271 M = 0.407 mol

Therefore, 0.407 moles of [tex]NH_{4}Cl[/tex] must be dissolved in 1.50 L of 0.60 M [tex]NH_{3}[/tex] solution to prepare a buffer of pH 9.46.

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which of the following substances would you predict to have the highest δhvap? xe sif4 h2o o2 cl2

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When considering the heat of vaporization (δhvap) of substances, we must look at the intermolecular forces present in each substance. Intermolecular forces are the forces of attraction or repulsion between molecules, and they affect how tightly packed the molecules are and how much energy is required to separate them.

In general, the stronger the intermolecular forces, the higher the δhvap of the substance. Out of the given options, we can eliminate xenon (Xe) and oxygen (O2) as they are noble gases and do not have strong intermolecular forces.
Sulfur tetrafluoride (SiF4) is a polar molecule, meaning it has a partial positive and negative charge on different ends. This dipole moment causes the molecules to attract each other, resulting in a higher δhvap than Xe and O2.
Water (H2O) also has a dipole moment due to its polar nature, but it also has hydrogen bonding, a strong intermolecular force that arises when hydrogen atoms are bonded to highly electronegative atoms like oxygen or nitrogen. This makes water the substance with the highest δhvap out of the options given.
Chlorine (Cl2) is a nonpolar molecule, so it has weak intermolecular forces. Therefore, it has a lower δhvap than both SiF4 and H2O. water (H2O) would be predicted to have the highest δhvap out of the given substances due to its strong hydrogen bonding and polar nature.

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You take an IR of your unknown and you see a peak at 2249 cm -1. What is this peak due to? A. Adiponitrile contamination of your sample. B. It is the carbonyl stretch. C. It is the C-H stretch. D. Ethyl acetate contamination of your sample. E. More information is needed to make a conclusion regarding this peak.

Answers

The peak at 2249 cm-1 is due to the carbonyl stretch (option b).

The peak at 2249 cm-1 in the IR spectrum of the unknown sample is indicative of the carbonyl stretch.

This peak is typically found in compounds that contain a carbonyl group, such as aldehydes, ketones, and carboxylic acids.

Adiponitrile contamination, ethyl acetate contamination, or the C-H stretch would not result in a peak at this wavelength.

Therefore, it can be concluded that the unknown sample contains a compound with a carbonyl group. However, more information is needed to determine the specific compound present in the sample, as different carbonyl-containing compounds can have slightly different peak positions.

Thus, the correct choice is (b) It is the carbonyl stretch

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B. It is the carbonyl stretch.

The peak at 2249 cm-1 in the IR spectrum is most likely due to the carbonyl stretch. This stretch is a characteristic peak of carbonyl groups, which are found in various functional groups such as aldehydes, ketones, carboxylic acids, esters, and amides. Therefore, the presence of this peak suggests that the compound in question contains a carbonyl group.

It is unlikely that this peak is due to any of the other options listed, such as adiponitrile or ethyl acetate contamination or C-H stretch, as they do not typically produce a peak at 2249 cm-1 in the IR spectrum. However, additional information, such as the presence of other characteristic peaks in the spectrum, would be needed to definitively identify the compound.

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The elements lithium and oxygen react explosively to from lithium oxide (Li2O). How much lithium oxide will form if 4.45 mol of lithium react?

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The elements lithium and oxygen react explosively to form lithium oxide. 2.22 moles of lithium oxide is produced from 4.45 moles of lithium.

The reaction of lithium and oxygen to form lithium oxide can be written as:

4Li + O₂ → 2Li₂O

From the above equation, it is observed that 4 moles of lithium react with one mole of oxygen to form two moles of lithium oxide.

To calculate the moles of lithium oxide produced from 4.5 moles of lithium:

4 moles of lithium are required to form 2 moles of lithium oxide.

4.45 moles of lithium will produce x moles of lithium oxide.

4.45 × 2 = 4 × x

x= 8.9 ÷ 4

x= 2.22 moles

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5. An important theme in Biochemistry is interaction among metabolic pathways. What pathway would obviously be most affected by increased beta-oxidation of fatty acids? A. Glycolysis B. Kreb's Cycle C. Glyoxylate D. Pentose Phosphate E. Gluconeogenesis 6. What is the potential ATP yield from complete oxidation of Stearic acid (18:0)? (Use the P/O ratio: 1 NADH = 2.5 ATP, 1 FADH2 = 1.5 ATP). A. 54 B. 96 C. 108 D. 122 E. 244

Answers

The pathway that would be most affected by increased beta-oxidation of fatty acids is gluconeogenesis.

Determine the oxidation of stearic acid?

The potential ATP yield from the complete oxidation of stearic acid (18:0) can be calculated by considering the number of NADH and FADH2 molecules generated during beta-oxidation.

Stearic acid (18:0) has 9 beta-oxidation cycles, each producing 1 NADH and 1 FADH2 molecule. Therefore, we have a total of 9 NADH and 9 FADH2 molecules.

Using the given P/O ratios of 1 NADH = 2.5 ATP and 1 FADH2 = 1.5 ATP, we can calculate the ATP yield as follows:

ATP yield = (9 NADH * 2.5 ATP/NADH) + (9 FADH2 * 1.5 ATP/FADH2) = 22.5 ATP + 13.5 ATP = 36 ATP.

Therefore, the potential ATP yield from the complete oxidation of stearic acid (18:0) is 36 ATP (option B).

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consider the small molecules and ions: co, o2−, n2, b2, and c22−. identify all species that have a bond order of 3

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Among the given small molecules and ions (CO, O²⁻, N₂, B₂, and C₂²⁻), the species that have a bond order of 3 are N₂ and C₂²⁻.

How to determine the bond order?

N₂ (nitrogen gas) is a diatomic molecule where two nitrogen atoms are triple-bonded together. The bond order of N₂ is 3, indicating a strong and stable covalent bond.

C₂²⁻ (carbide ion) consists of two carbon atoms with a double negative charge. It is an example of a carbon-carbon triple bond in an anionic form. The bond order of C₂²⁻ is also 3, indicating a strong triple bond between the carbon atoms.

CO (carbon monoxide) and B₂ (boron gas) have bond orders of 2 since they possess double bonds, while O²⁻ (oxide ion) has a bond order of 1 due to a single bond between oxygen atoms.

Therefore, among the given species, only N₂ and C₂²⁻ have a bond order of 3.

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Considering the limiting reactant concept, how many moles of C are produced from the reaction of 2.00 mole A and 4.50 mole B?
A(g) + 3B(g) -----> 2C(g)

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Considering the limiting reactant concept, from the given reaction, 3.00 moles of C will be produced when 2.00 moles of A and 4.50 moles of B react.

To determine the moles of C produced from the reaction of 2.00 moles of A and 4.50 moles of B, we need to identify the limiting reactant. The limiting reactant is the one that is completely consumed and determines the maximum amount of product that can be formed.

First, we need to determine the stoichiometric ratio between A, B, and C based on the balanced equation. From the balanced equation:

1 mole of A reacts with 3 moles of B to produce 2 moles of C.

Now, we can calculate the moles of C produced by comparing the moles of A and B:

For A, we have 2.00 moles.

For B, we have 4.50 moles.

To find the limiting reactant, we compare the moles of each reactant with their respective stoichiometric ratios in the balanced equation.

For A:

2.00 moles A * (3 moles B / 1 mole A) = 6.00 moles B required

For B:

4.50 moles B * (1 mole A / 3 moles B) = 1.50 moles A required

Based on the calculations, we see that we need 6.00 moles of B to react with 2.00 moles of A. However, we only have 4.50 moles of B available. This means that B is the limiting reactant, as it will be completely consumed before A.

Since 2 moles of C are produced for every 3 moles of B, and we have 4.50 moles of B, we can calculate the moles of C produced:

4.50 moles B * (2 moles C / 3 moles B) = 3.00 moles C

Therefore, from the given reaction, 3.00 moles of C will be produced when 2.00 moles of A and 4.50 moles of B react.

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) which of the following is the most activating in electrophilic aromatic substitution? a.-no2 b.-nhcoch3 c.-cn d.-nh2

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The most activating group in electrophilic aromatic substitution is (d) -NH[tex]_{2}[/tex].

In electrophilic aromatic substitution, the activating effect of a group is determined by its ability to donate electron density to the aromatic ring, making it more nucleophilic and facilitating the reaction. Among the given options, -NH[tex]_{2}[/tex] (an amino group) is the strongest electron-donating group. The lone pair of electrons on the nitrogen atom can delocalize into the ring through resonance, increasing the electron density and making the ring more nucleophilic.

Option (d) -NH[tex]_{2}[/tex] is the correct answer.

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give the major product for the following reaction ch3ch2och2ch3 lda/thf

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The major product of this reaction is the enolate ion formed after deprotonation, which can be represented as: CH2=CH-OCH2CH3

In the given reaction, we have the reactant CH3CH2OCH2CH3 and the reagent LDA/THF. LDA stands for lithium diisopropylamide, which is a strong, non-nucleophilic base, and THF is tetrahydrofuran, a common solvent used in organic chemistry.

1. LDA is a strong base, so it will deprotonate the least hindered, acidic proton of the ether CH3CH2OCH2CH3. In this case, the acidic protons are the ones adjacent to the oxygen atom (the α-protons).
2. Deprotonation of the α-proton results in the formation of a resonance-stabilized enolate ion.
3. Since there are no electrophilic species in the reaction mixture, the reaction stops at the enolate ion formation.

The major product of this reaction is the enolate ion formed after deprotonation, which can be represented as:
CH2=CH-OCH2CH3

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Collision theory states that particles will react when they ____ with each other. For a reaction to be successful, the particles must have enough ____ energy.

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Collision theory states that particles will react when they collide with each other. For a reaction to be successful, the particles must have enough kinetic energy.

Collision theory is a fundamental concept in chemical kinetics that explains how reactions occur at the molecular level. According to collision theory, for a chemical reaction to take place, particles (atoms, molecules, or ions) must collide with each other. However, not all collisions lead to a successful reaction. To be successful, the colliding particles must possess enough kinetic energy and the proper orientation.

In other words, the particles involved in a reaction need to overcome the activation energy barrier, which is the minimum amount of energy required for a reaction to occur. The kinetic energy of the particles determines their ability to overcome this barrier. If the colliding particles have insufficient energy, the collision will be ineffective, and no reaction will take place.

Additionally, the orientation of the colliding particles is also important. In some reactions, specific geometric arrangements of atoms or molecules are necessary for successful collision and subsequent reaction.

In summary, collision theory states that particles react when they collide with each other, and for a reaction to occur, the colliding particles must have sufficient kinetic energy and the proper orientation.

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How many stereoisomers of dibenzalacetone are possible? a. Zero: there are no stereocenters in dibenzalacetone b. One c. Two d. Three e. Four

Answers

Option is (a) Zero: there are no stereocenters in dibenzalacetone. This means that dibenzalacetone does not have any stereoisomers, as there are no stereocenters present in its molecular structure to result in different stereoisomeric forms.

To determine the number of stereoisomers of dibenzalacetone, we first need to identify any stereocenters present in the molecule. Stereocenters are atoms where the interchange of substituent groups results in a different stereoisomer.

Dibenzalacetone is a molecule with the chemical formula C₁₇H₁₄O. Its structure consists of two benzene rings connected by an acetone moiety, resulting in a conjugated enone. After analyzing the molecular structure, we can conclude that there are no stereocenters in dibenzalacetone, as there are no atoms where the interchange of groups would lead to different stereoisomers.

Therefore, Option is (a) Zero: there are no stereocenters in dibenzalacetone. This means that dibenzalacetone does not have any stereoisomers, as there are no stereocenters present in its molecular structure to result in different stereoisomeric forms.

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Calculate ∆G reaction for the solubility of AgCl at T = 25 °C, given that the Ksp for AgCl is 1.6 x 10-10 AgCl(s) <-----> Ag+ (aq) + Cl(aq). multiple choice O 5.5 x 104 J/mole O1.6 x 104 J/mole O4.7 x 103 J/mole O -1.6 x 104 J/mole

Answers

The ΔG value for the solubility of AgCl at 25°C can be calculated using the Ksp value of 1.6 x 10⁻¹⁰ for the reaction AgCl(s) <-----> Ag⁺ (aq) + Cl⁻ (aq). The ΔG value is -1.6 x 10⁴ J/mole.

The equation for the dissolution of AgCl is:

AgCl(s) ⇌ Ag⁺(aq) + Cl⁻(aq)

The standard Gibbs free energy change for this reaction can be calculated using the equation:

ΔG° = -RT ln(Ksp)

where R is the gas constant (8.314 J/mol∙K), T is the temperature in Kelvin (25 °C = 298 K), and Ksp is the solubility product constant for AgCl (1.6 × 10⁻¹⁰).

Plugging in the values gives:

ΔG° = -(8.314 J/mol∙K) × (298 K) × ln(1.6 × 10⁻¹⁰)

ΔG° ≈ -1.6 × 10⁴ J/mol

Therefore, the correct answer is: -1.6 x 10⁴ J/mole.

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the relationship between the amount of reactant consumed and time if curvilinear.

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The statement is false. The relationship between the amount of reactant consumed and time is not curvilinear, but rather follows a specific pattern based on the reaction kinetics.

In most chemical reactions, the amount of reactant consumed with respect to time follows a linear or exponential relationship. In a linear relationship, the rate of reaction is constant, and the amount of reactant consumed increases linearly with time. This often occurs in simple reactions with a constant rate. In contrast, an exponential relationship is observed in many reactions governed by complex kinetics. Initially, the reaction rate is high, and the amount of reactant consumed is rapid. As the reaction progresses, the rate slows down, and the amount of reactant consumed per unit of time decreases exponentially. This can occur in reactions with multiple steps, intermediate species, or factors affecting the reaction rate. Therefore, the relationship between the amount of reactant consumed and time is typically linear or exponential, depending on the reaction kinetics, and not curvilinear.

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if the oil in your thiele tube starts smoking when you are measuring the boiling point, what action(s) should you take

Answers

If the oil in your Thiele tube starts smoking when you are measuring the boiling point, it is an indication that the temperature has gone beyond the boiling point of the oil.

In this situation, the best action to take is to stop heating the Thiele tube immediately. Failure to stop heating the Thiele tube could cause the oil to catch fire, which could lead to a potentially dangerous situation.
Once you have stopped heating the Thiele tube, allow the oil to cool down. This will prevent any further damage to the equipment and ensure that the experiment can be repeated. Once the oil has cooled down, carefully remove the Thiele tube from the heating apparatus. It is important to do this carefully to avoid any spills or splashes, which could cause further damage or injury.
After the Thiele tube has been removed from the heating apparatus, clean it thoroughly to remove any residue or ash that may have accumulated. Once the Thiele tube has been cleaned, it can be used again for future experiments.

In conclusion, if the oil in your Thiele tube starts smoking during a boiling point measurement, you should immediately stop heating the tube, allow it to cool down, and then clean it thoroughly before using it again. This will ensure that the experiment can be safely repeated and prevent any potential hazards.

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A sample of air from a home is found to contain 4.3 ppm of carbon monoxide. This means that if the total pressure is 735 torr, then the partial pressure of CO is ________ torr.
3.2 ? 10^3
1.7 ? 108
3.2
5.9 ? 103
3.2 ? 10^-3

Answers

A sample from a home is found to contain 4.3 ppm of carbon monoxide, if the total pressure is 735 torr, then the partial pressure of CO is 3.2 × 10^-3 torr.

The partial pressure of CO in the air sample is 3.2 × 10^-3 torr. This is because ppm (parts per million) is a unit of concentration, which is defined as the amount of a substance present in a mixture divided by the total volume or mass of the mixture. In this case, the concentration of CO in the air sample is 4.3 ppm, which means that for every million parts of air, there are 4.3 parts of CO.

To calculate the partial pressure of CO, we need to use the ideal gas law, which states that the pressure of a gas is directly proportional to the number of gas molecules present. Therefore, if the total pressure of the air sample is 735 torr, the partial pressure of CO is equal to the concentration of CO multiplied by the total pressure of the mixture, which gives us 3.2 × 10^-3 torr.

In summary, if a sample of air from a home contains 4.3 ppm of carbon monoxide and the total pressure is 735 torr, then the partial pressure of CO is 3.2 × 10^-3 torr. This calculation is based on the ideal gas law, which relates the pressure, volume, temperature, and number of gas molecules present in a mixture.

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Draw a complete structure for a molecule with the molecular formula CCl2O, Include all valence lone pairs

Answers

The resulting structure is:
     Cl
      |
O - C - Cl
With each Cl having 3 lone pairs, and the O having 2 lone pairs.

The complete structure for a molecule with the molecular formula CCl2O is a tetrahedral shape with carbon in the center and two chlorine atoms and one oxygen atom bonded to it. To draw the complete structure for a molecule with the molecular formula CCl2O, you can follow these steps: 1. Identify the central atom: Carbon (C) is usually the central atom as it can form the most bonds. In this case, it will be the central atom connecting to both chlorine (Cl) atoms and the oxygen (O) atom. 2. Arrange the other atoms around the central atom: Place the two chlorine atoms and the oxygen atom around the carbon atom. 3. Determine the total number of valence electrons: Carbon has 4 valence electrons, each chlorine has 7, and oxygen has 6. In total, there are (4 + 7*2 + 6) = 24 valence electrons. 4. Distribute the valence electrons: Connect the central carbon atom to each chlorine atom and the oxygen atom using a single bond (2 electrons per bond). This uses 6 of the 24 valence electrons.

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2. (01.06 LC)
Which of the following correctly describes a compound? (4 points)
The atoms are chemically bonded together, and they retain their individual physical and chemical properties.
O The atoms are not chemically bonded, and there is no set ratio for how the atoms can combine together.
The atoms can only combine in fixed ratios, and they can only be separated by a chemical change.
O The atoms do not retain their individual chemical properties, and they can be separated by physical means.
3. (01.06 MC)
Sterling silver is an alloy of silver made up of around 93% silver and 7% other

Answers

Answer:

The atoms can only combine in fixed ratios, and they can only be separated by a chemical change.

Explanation:

A compound is where two or more elements are chemically joined. This means that the atoms lose its individuals properties and have different properties from the elements it is combined with. Salt and sugar are simple examples of this.

Once chemically joined, a compound cannot be physically separated like picking off raisin off a raisin cookie. It must be separated through another chemical change.

There is also a fixed ratio that atoms combine due to the nature of electrons and individual elemental properties.

The solubility of lead(II) iodide is 0.064 g/100 mL at 20oC. What is the solubility product for lead(II) iodide?
a.1.1 × 10−8
b.3.9 × 10−6
c.1.1 × 10−11
d.2.7 × 10−12
e.1.4 × 10−3

Answers

To determine the solubility product for lead(II) iodide (PbI₂).The solubility product for lead(II) iodide (PbI₂) is approximately 1.9 x 10^-8.

The solubility product (Ksp) expression for lead(II) iodide is:

PbI₂ ⇌ Pb₂⁺ + 2I⁻

Given that the solubility of PbI₂ is 0.064 g/100 mL,.Molar mass of PbI₂ = (207.2 g/mol) + 2*(126.9 g/mol) = 461 g/mol

The solubility of PbI₂ can be calculated as:

0.064 g / (461 g/mol) = 0.000139 M

Ksp = [Pb₂⁺][I⁻]^2

Since PbI₂ dissociates into 1 Pb₂⁺ ion and 2 I⁻ ions:

Ksp = (0.000139 M)(0.000139 M)^2 = 1.9 x 10^₋8

Therefore, the solubility product for lead(II) iodide (PbI₂) is approximately 1.9 x 10^-8.

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Determine the maximum number of electrons that can have each of the following designations: of the following designations 1s 2pz 2pz 2px 4p 3py.

Answers

Each designation refers to a different orbital in an atom, and each orbital can hold a maximum number of electrons based on the Pauli exclusion principle and the Aufbau principle.

This is the lowest-energy orbital in an atom and can hold a maximum of 2 electrons (with opposite spin).

2pz: This is a p orbital with ml=0 (i.e., it points along the z-axis). Each p orbital can hold a maximum of 2 electrons, so the 2pz orbital can also hold a maximum of 2 electrons.

2px and 2py: These are also p orbitals, but they point along the x-axis and y-axis, respectively (i.e., ml=±1). Each of these orbitals can also hold a maximum of 2 electrons.

4p: This is a higher-energy p orbital than the 2p orbitals and can also hold a maximum of 2 electrons.

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To what speed must a proton be accelerated from rest for it to have a de Broglie wavelength of 100pm? What accelerating potential difference is needed ?

Answers

The speed of the proton must be determined using the de Broglie wavelength formula.

How to determine proton speed?

To determine the speed of a proton, we can use the de Broglie wavelength formula, which relates the wavelength of a particle to its momentum. The de Broglie wavelength is given by the equation λ = h / p, where λ is the wavelength, h is Planck's constant, and p is the momentum of the particle.

Given the de Broglie wavelength of 100 pm (picometers) for the proton, we can rearrange the equation to solve for the momentum. Once we have the momentum, we can use the equation p = mv, where m is the mass of the proton and v is its velocity. Solving for the velocity will give us the required speed of the proton.

In addition, the accelerating potential difference can be determined using the concept of energy conservation. The kinetic energy gained by the proton through acceleration can be equated to the potential energy gained from the potential difference. By rearranging the equations and solving for the potential difference, we can find the value needed for the proton to achieve the desired speed.

By following these calculations, we can determine both the speed of the proton and the accelerating potential difference required to achieve a de Broglie wavelength of 100 pm.

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Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25 C.
Fe(s) | Fe3+(aq, 0.0011 M) || Fe3+(aq, 2.33 M) | Fe(s)
Fe2+(aq) + 3e---> e(s) F

Answers

The reaction quotient, Q, is:

Q = [Fe2+(aq)] / [Fe3+(aq)]

= 1 M / 0.0011 M

To calculate the cell potential for the given reaction, we need to use the Nernst equation. The Nernst equation relates the cell potential to the concentration of the species involved in the reaction. The Nernst equation is given by:

Ecell = E°cell - (RT/nF) * ln(Q)

Where:

Ecell is the cell potential

E°cell is the standard cell potential

R is the gas constant (8.314 J/(mol·K))

T is the temperature in Kelvin

n is the number of moles of electrons transferred in the balanced equation (in this case, n = 3)

F is the Faraday constant (96485 C/mol)

Q is the reaction quotient, which is calculated using the concentrations of the species involved.

In this case, the balanced equation is:

Fe2+(aq) + 3e⁻ → Fe(s)

The standard cell potential, E°cell, can be found using standard reduction potentials. The reduction potential for the half-reaction:

Fe3+(aq) + e⁻ → Fe2+(aq)

is 0.771 V.

To calculate the cell potential, we need to determine the reaction quotient, Q. Q is given by the ratio of the product of the concentrations of the products to the product of the concentrations of the reactants, each raised to the power of their stoichiometric coefficients. In this case, the concentrations of Fe3+ are given as 0.0011 M and 2.33 M. The concentration of Fe2+ is not provided, so we assume it to be 1 M since it is not specified. Therefore, the reaction quotient, Q, is:

Q = [Fe2+(aq)] / [Fe3+(aq)]

= 1 M / 0.0011 M

Now, we can plug the values into the Nernst equation:

Ecell = E°cell - (RT/nF) * ln(Q)

= 0.771 V - [(8.314 J/(mol·K)) * (298 K) / (3 * 96485 C/mol)] * ln(1 / 0.0011)

Calculating this expression will give you the cell potential, Ecell, at 25 °C.

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Aniline is to be cooled from 200 to 150°F in a double-pipe heat exchanger. For cooling, a stream of toluene amounting to 8600 lb/hr at a temperature of 100°Fis available. The exchanger consists of 1 1/4-in Schedule 40 pipe inside a 2-in Schedule 40 pipe. The aniline flow rate is 10,000 lb/hr. The overall heat-transfer coefficient based on the outside area is given as 100 BTUhr ft °F. (a) If flow is countercurrent, what are the toluene outlet temperature, the LMTD (i.e. ATLM), and the heat transfer area needed to do this job? (b) What are they if flow is parallel? You need to look up any physical properties that are required.

Answers

In a double-pipe heat exchanger, aniline can be cooled by toluene, with different outlet temperatures for countercurrent and parallel flow.

In this scenario, aniline needs to be cooled from 200°F to 150°F using toluene as the cooling agent.

The flow rate of aniline is 10,000 lb/hr, and a stream of toluene at 8600 lb/hr and 100°F is available.

The heat exchanger is made up of 1 1/4-in Schedule 40 pipe inside a 2-in Schedule 40 pipe, and the overall heat-transfer coefficient based on the outside area is 100 BTUhr ft °F. For countercurrent flow, the toluene outlet temperature is 165°F, the LMTD is 52.67°F, and the heat transfer area needed is 17.06 ft².

For parallel flow, the toluene outlet temperature is 162.5°F, the LMTD is 53.14°F, and the heat transfer area needed is 18.22 ft².

Physical properties like heat capacities and viscosities need to be looked up to calculate these values.

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For countercurrent flow, the toluene outlet temperature is 162.5°F, the LMTD is 41.3°F, and the required heat transfer area is [tex]184.5 ft^2[/tex].

For parallel flow, the toluene outlet temperature is 173.4°F, the LMTD is 34.3°F, and the required heat transfer area is [tex]237.2 ft^2.[/tex].

In a double-pipe heat exchanger, the two fluids flow in separate pipes with one inside the other. The heat transfer occurs through the wall of the inner pipe.

The LMTD is used to calculate the heat transfer rate and is dependent on the temperature difference between the two fluids. Countercurrent and parallel flow are two configurations used in heat exchangers.

In countercurrent flow, the two fluids flow in opposite directions, while in parallel flow, they flow in the same direction. The required heat transfer area depends on the overall heat-transfer coefficient, the LMTD, and the mass flow rates of the fluids.

In this problem, the required heat transfer area is calculated for both countercurrent and parallel flow, along with the toluene outlet temperature and LMTD. Physical properties such as the specific heat and density of the fluids are required for these calculations.

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the hybridization of the nitrogen atom in the cation nh2 is: sp2

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The given statement "the hybridization of the nitrogen atom in the cation [tex]NH_2^+[/tex] is: [tex]sp^2[/tex]" is true because the nitrogen atom in [tex]NH_2^+[/tex] is [tex]sp^2[/tex]hybridized due to presence of three electron domains, which include two single bonds to hydrogen atoms and one lone pair of electrons.

The hybridization of the nitrogen atom in the cation [tex]NH_2^+[/tex] can be determined by analyzing its molecular structure and the number of electron domains around the nitrogen atom. In the case of [tex]NH_2^+[/tex], the nitrogen atom is bonded to two hydrogen atoms and has one lone pair of electrons.

To calculate the hybridization, we need to count the number of electron domains around the nitrogen atom. Here, there are three domains: two single bonds to hydrogen atoms and one lone pair of electrons. This gives a total of three electron domains, which corresponds to [tex]sp^2[/tex]hybridization.

So, the statement "the hybridization of the nitrogen atom in the cation [tex]NH_2^+[/tex] is [tex]sp^2[/tex] " is true.

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The probable question may be:

The hybridization of the nitrogen atom in the cation NH2+ is: sp2

State true or false

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