The heat of vaporization (DHovap) of benzene at 298 Kelvin is 33.89 kJ/mol and its vapor pressure is 96 torr. Calculate Keq at 298 Kelvin.

Answers

Answer 1

The heat of vaporization (DHovap) of benzene at 298 Kelvin is 33.89 kJ/mol and its vapor pressure is 96 torr.

To calculate Keq at 298 Kelvin, we will use the following equation; Delta G = -RT ln Keq

Where;

ΔG = Gibbs Free Energy

R = Gas constant

T = Temperature

Keq = Equilibrium constant

Given:

DHovap = 33.89 kJ/mo

lT = 298

KPH2O = 96 torr

First, we will convert vapor pressure to atm using the following;1 atm = 760 torrPH2O = 96 torr/760 torr/atm= 0.1263 atm. Now we can calculate ΔG using the following equation;ΔG = DHovap - RT ln(PH2O). Where; R = 8.314 J/mol.K Note that we need to convert kJ to J.1 kJ = 1000 JDHovap = 33.89 kJ/mol = 33.89 x 1000 J/mol DHovap = 33,890 J/molΔG = (33,890 J/mol) - (8.314 J/mol.K)(298 K)ln(0.1263 atm)ΔG = - 20602.88 J/mol. Now, we can solve for Keq by rearranging the equation for ΔG;ΔG = -RT lnKeqKeq = e^(-ΔG/RT)Keq = e^(-(-20602.88 J/mol)/(8.314 J/mol.K)(298 K))Keq = 2.37 x 10^21Answer: The Keq at 298 Kelvin is 2.37 x 10^21.

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Related Questions

At the center of the Sun, fusion converts hydrogen into Group of answer choices plasma. hydrogen compounds. radioactive elements like uranium and plutonium. helium, energy, and neutrinos. radiation and elements like carbon and nitrogen.

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At the center of the Sun, fusion converts hydrogen into helium, energy, and neutrinos. Option C is the correct answer.

The core of the Sun is where helium is produced from hydrogen. This phenomenon is known as nuclear fusion. Four hydrogen atoms fuse together to form each helium atom. The process involves converting a fraction of the mass into energy. Option C is the correct answer.

The Sun is a huge ball of gas that radiates brightly at all angles and is highly hot. Fusion is difficult to replicate on Earth, but it is a vital process in the cores of the Sun and other stars. Temperatures in this area are high enough for hydrogen and helium atoms to collide and create helium atoms, which releases enormous amounts of energy in a number of ways. The Sun generates energy in the form of light, which continues to refract around inside it as if the Sun were made of mirrors.

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The complete question is, "At the center of the Sun, fusion converts hydrogen into

A. plasma.

B. radiation and elements like carbon and nitrogen.

C. helium, energy, and neutrinos.

D. hydrogen compounds."

consider the following reaction.

mg(s) + 2HCl(aq) ——> MgCl2(aq) + H2 (g)

The total pressure of gas collected over water is 665.0 mmHg and the temperature is 23.0 C what is the pressure of hydrogen gas formed in mmHg

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Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)The total pressure of the gas collected over water is 665.0 mmHg. The temperature of the gas collected is 23.0°C. We need to calculate the pressure of hydrogen gas formed in mmHg

The given reaction is balanced and the stoichiometric coefficients of hydrogen gas are equal to 1.So, the volume of hydrogen gas is proportional to the moles of hydrogen gas. We will use the Ideal Gas Law to solve the problem.Ideal Gas LawPV = nRTWhere,P = pressure of the gasV = volume of the gasn = number of moles of the gasR = gas constantT = temperature of the gasWe can rearrange the Ideal Gas Law to get the expression for the pressure of the gas.P = (nRT) / VThe volume of the gas collected is not given directly.

But we can calculate it using the Dalton's Law of Partial Pressures.The total pressure of the gas collected is 665.0 mmHg. This pressure includes the partial pressure of water vapor. We need to subtract the pressure due to water vapor from the total pressure to get the partial pressure of hydrogen gas.PH2 = Ptotal - PH2O Water vapor is collected over the water surface and it exerts a partial pressure. The pressure due to water vapor is calculated using the vapor pressure of water at 23.0°C. The vapor pressure of water at 23.0°C is 21.1 mmHg.The partial pressure of hydrogen gas is,P H2 = Ptotal - PH2O= 665.0 - 21.1= 643.9 mmHgTherefore, the pressure of hydrogen gas formed in mmHg is 643.9 mmHg.

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The pH scale is a logarithmic scale, meaning that a solution with a pH of 1.00 has a concentration of hydronium (H3O ) _____ times _____ than a solution with a pH of 3.00

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The pH scale is a logarithmic scale, meaning that a solution with a pH of 1.00 has a concentration of hydronium (H₃O⁺) 100 times higher than a solution with a pH of 3.00.

The pH scale is indeed a logarithmic scale. The concentration of hydronium ions (H₃O⁺) in a solution can be related to its pH using the following equation:

pH = -log[H₃O⁺]

To compare the concentration of hydronium ions between a solution with a pH of 1.00 and a solution with a pH of 3.00, we can use the equation;

[H₃O⁺]1 / [H₃O⁺]2 = [tex]10^{(pH2-pH1)}[/tex]

Where [H₃O⁺]1 and [H₃O⁺]2 represent the concentrations of hydronium ions for solutions with pH values of 1.00 and 3.00, respectively.

Substituting the given pH values into the equation:

[H₃O⁺]1 / [H₃O⁺]2 = [tex]10^{(3.00-1.00)}[/tex]

[H₃O⁺]1 / [H₃O⁺]2 = 10²

[H₃O⁺]1 / [H₃O⁺]2 = 100

This means that a solution with a pH of 1.00 has a concentration of hydronium ions 100 times higher than a solution with a pH of 3.00.

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Potassium hydrogen phthalate is a solid, monoprotic acid frequently used in the laboratory to standardize strong base solutions. It has the unwieldy formula of KHC8H4O4. This is often written in shorthand notation as KHP. How many grams of KHP are needed to exactly neutralize 24.1 mL of a 0.452 M potassium hydroxide solution

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The balanced chemical equation for the neutralization of Potassium hydrogen phthalate (KHP) and Potassium Hydroxide (KOH) is shown below:KHC8H4O4 + KOH → K2H(C8H4O4)2 + H2ONumber of moles of KOH = concentration × volume = 0.452 M × 0.0241 L = 0.0109 moles of KOH

To completely neutralize the acid, the same number of moles of KHP are required as that of KOH. The molar ratio of KHP and KOH is 1:1.

Hence, the number of moles of KHP required is also 0.0109 moles.

Number of moles of KHP = number of moles of KOH = 0.0109 moles Molar mass of KHP = 204.22 g/mol Mass of KHP required = number of moles × molar mass= 0.0109 mol × 204.22 g/mol= 2.22 g

Therefore, 2.22 grams of KHP is required to exactly neutralize 24.1 mL of a 0.452 M potassium hydroxide solution.

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what is the molar mass of an unknown compound if 0.0216 g in 3.024 of benzene forms a solution that freezes at 5.206 c

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The molar mass of the unknown compound is approximately 267.07 g/mol.

Given to us is

Mass of unknown compound (solute) = 0.0216 g

Mass of benzene (solvent) = 3.024 g

Freezing point depression (ΔT) = 5.206 °C

First, let's calculate the molality (m) of the solution:

m = (moles of solute) / (mass of solvent in kg)

To find the moles of the solute, we need to calculate the moles of the unknown compound using its mass and molar mass:

moles of solute = (mass of solute) / (molar mass)

Next, we convert the mass of the solvent to kilograms:

mass of solvent = (mass of benzene) / 1000

Now, let's substitute the values into the freezing point depression equation:

5.206 = Kf × [(moles of solute) / (mass of solvent in kg)]

By rearranging the equation and solving for the molar mass:

Molar mass = (moles of solute) / (molality)

To obtain the final answer,we will perform the calculations:

Moles of solute = (0.0216 g) / (molar mass)

Mass of solvent = (3.024 g) / 1000

Molality = (moles of solute) / (mass of solvent in kg)

Molar mass = (moles of solute) / (molality)

Therefore, using the given values and performing the calculations, the molar mass of the unknown compound is approximately 267.07 g/mol.

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Compare the following substances taking into account their physical properties. kitchen salt and sugar

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Kitchen salt (sodium chloride) and sugar (sucrose) are both common substances but differ in their physical properties. Salt is a crystalline solid with a high melting point, while sugar is also a crystalline solid but has a lower melting point.

Salt, or sodium chloride (NaCl), exists as a white crystalline solid. It has a high melting point of 801°C, meaning it remains solid at room temperature. Salt is highly soluble in water, forming an electrolyte solution, and it exhibits a characteristic salty taste.

Sugar, or sucrose (C12H22O11), is also a crystalline solid but with a lower melting point compared to salt. Sugar melts at around 186-186.5°C, which is lower than the melting point of salt. Like salt, sugar is soluble in water, forming a sweet-tasting solution.

In terms of taste, salt imparts a salty flavor to food, while sugar provides a sweet taste. These differences in physical properties make salt and sugar distinct substances with various uses in cooking and other applications.

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A 2.96 g sample of iron ore is transformed to a solution of iron(II) sulfate, . This solution is titrated with 0.160 M (potassium dichromate). If it requires 27.9 mL of potassium dichromate solution to titrate the iron(II) sulfate solution, what is the percentage of iron in the ore?

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The percentage of iron in the ore is 32.1%. To calculate the percentage of iron in the ore, we need to use the following formula:

% iron = (moles of iron(II) sulfate) x (molar mass of iron) x 100 / (mass of iron ore)

Here are the given values:

Mass of iron ore: 2.96 g

Volume of potassium dichromate solution: 27.9 mL = 0.0279 L

Molarity of potassium dichromate solution: 0.160 M

To use the formula, we need to first calculate the moles of iron(II) sulfate in the solution. This can be done using the balanced chemical equation for the reaction between iron(II) sulfate and potassium dichromate:

6 FeSO₄+ K₂Cr₂O₇ + 7 H₂SO₄ → 3 Fe₂(SO₄)₃ + Cr₂(SO₄)₃ + K₂SO₄ + 7 H₂O

From the equation, we can see that 1 mole of potassium dichromate reacts with 6 moles of iron(II) sulfate. Therefore, the number of moles of iron(II) sulfate in the solution is:

moles of FeSO₄ = (0.160 M) x (0.0279 L) x 6 = 0.0271 moles

Next, we can use the formula to calculate the percentage of iron in the ore:

% iron = (moles of iron(II) sulfate) x (molar mass of iron) x 100 / (mass of iron ore)

The molar mass of iron is 55.85 g/mol. Substituting the known values and solving for % iron, we get:

% iron = (0.0271 moles) x (55.85 g/mol) x 100 / (2.96 g) = 32.1%

Therefore, the percentage of iron in the ore is 32.1%.

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Question Mode Multiple Choice Question The electron transport chain directly associated with PSII is used to generate ______, while the electron transport chain directly associated with PSI is used to generate ______.

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In the thylakoid membrane of organisms ranging from cyanobacteria to higher plants, there is a huge membrane protein complex called photosystem II (PSII), also known as water-plastoquinone oxidoreductase. PSII is used to generate ATP and PSI is used to generate NADPH.

Light is absorbed by the Photosystem (II), which causes a series of light-induced electron transfer events that divide water molecules. A proton gradient is produced by the oxidation of water, which also produces hydrogen ions. The ATP synthase complex uses a gradient in this way to produce ATP.

NADPH, a moderate-energy hydrogen transporter, is created by photosystem I. In addition to producing a proton-motive force that is used to create ATP, Photosystem I absorbs photon energy. Compared to Photosystem II, PSI has much more cofactors—more than 110.

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For the following reaction: cuclo3 + naoh = cuoh + naclo3
list the:
- spectator ions
- precipitate

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In the reaction between [tex]Cu(ClO3)2[/tex] and NaOH, the spectator ions are Na+ and [tex]ClO3-[/tex], while the precipitate formed is [tex]Cu(OH)2[/tex].

In the given reaction, [tex]Cu(ClO3)2[/tex] reacts with NaOH to form [tex]Cu(OH)2[/tex] and NaClO3. The spectator ions are the ions that do not participate in the formation of the precipitate and remain unchanged throughout the reaction.

The ionic equation for the reaction is:

[tex]Cu(ClO3)2[/tex] + 2NaOH → [tex]Cu(OH)2[/tex] + 2NaClO3

In this equation, the Cu2+ ion from [tex]Cu(ClO3)2[/tex] reacts with the OH- ion from NaOH to form the insoluble precipitate [tex]Cu(OH)2[/tex]. The Na+ ion and the [tex]ClO3-[/tex] ion from NaOH and [tex]Cu(ClO3)2[/tex], respectively, are spectator ions.

Spectator ions do not undergo any chemical changes and can be found on both sides of the equation. They are present in the solution but do not directly participate in the formation of the precipitate. In this case, Na+ and [tex]ClO3-[/tex] ions are spectator ions.

The precipitate formed in the reaction is [tex]Cu(OH)2[/tex]. It is insoluble in water and separates from the solution as a solid. The precipitate can be identified by its characteristic appearance and by observing the formation of a cloudy or milky solution.

To summarize, the spectator ions in the reaction are Na+ and ClO3-, while the precipitate formed is[tex]Cu(OH)2[/tex].

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The change in enthalpy of a reaction is equal to the enthalpy of the _____ minus the enthalpy of the _____.

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The change in enthalpy of a reaction is equal to the enthalpy of the products minus the enthalpy of the recatants.

Enthalpy is a measure of the heat content of a substance or system, and it is expressed in units of joules per mole (J/mol). In a chemical reaction, the enthalpy change is the amount of heat absorbed or released by the system during the reaction.

The enthalpy of the products is the enthalpy of the substances that are formed as a result of the reaction, while the enthalpy of the reactants is the enthalpy of the substances that are consumed during the reaction.

The change in enthalpy can be calculated using the following equation:

ΔH = Hf - Hc

Where ΔH is the change in enthalpy, Hf is the enthalpy of the products, and Hc is the enthalpy of the reactants.

It is important to note that the enthalpy change of a reaction can be affected by factors such as the temperature and pressure of the reaction, as well as the presence of catalysts or other substances that affect the enthalpy of the reaction.

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1. ) Calculate the pH of a solution formed by mixing 200. 0 mL of 0. 300 M NaHSO4


with 200. 0 mL of 0. 200 M Na2SO4 and 1. 0 ml 1. 00 M NaOH. The Ka2 for H2SO4


is 1. 2 x 10^-2.

Answers

The pH of the given solution is 3.4.The number of moles of Na2SO4 = Molarity × volume of Na2SO4= 0.2 × (200/1000) = 0.04 moles.

Here's the solution to your problem: The given concentration of NaHSO4 is 0.3 M Volume of NaHSO4 is 200 ml The number of moles of NaHSO4 = Molarity × volume of NaHSO4= 0.3 × (200/1000) = 0.06 moles. The given concentration of Na2SO4 is 0.2 M Volume of Na2SO4 is 200 ml The number of moles of Na2SO4 = Molarity × volume of Na2SO4= 0.2 × (200/1000) = 0.04 moles. Now, we have to add 1 ml of 1.00 M NaOH to the solution. Moles of NaOH = 1.00 × (1/1000) = 0.001 moles. Since H2SO4 is a diprotic acid, it will have two dissociation constants, as represented below:H2SO4 → H+ + HSO4^-Ka1 = 1.3 × 10^-2HSO4^- → H+ + SO4^-2Ka2 = 1.2 × 10^-2NaHSO4 will dissociate as follows:NaHSO4 → Na+ + HSO4^-HSO4^- → H+ + SO4^-2The first dissociation constant Ka1 is negligible compared to the second dissociation constant Ka2, thus we can ignore it.HSO4^- + NaOH → Na+ + H2O + SO4^-2Initial concentration of HSO4^- = moles/volume= (0.06 / 0.4) = 0.15 M Initial concentration of NaOH = moles/volume= (0.001 / 0.201) = 0.005 M Let x be the concentration of H+ ions produced from the reaction between HSO4^- and NaOH. Moles of NaOH = Moles of HSO4^-Thus, (0.005) = x Volume of final solution = Volume of NaHSO4 + Volume of Na2SO4 + Volume of NaOH= (200 + 200 + 1) ml= 401 ml[H+] = x[H+][HSO4^-] / [Na+] = Ka2 x = Ka2 * [Na+] / [HSO4^-]= 1.2 × 10^-2 × 0.005 / 0.15= 4 × 10^-4MNow, we can calculate the pH of the solution: pH = -log[H+]pH = -log(4 × 10^-4)= 3.4Hence, the pH of the given solution is 3.4.

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th silberberg, sample problem 13.5. find the concentration of calcium ion (in ppm) in a 2.94 g pill that contains 45.1 mg of ca2 . enter to 0 decimal places.

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The concentration of calcium ion in the pill is approximately 191,156 ppm

To find the concentration of calcium ion (Ca2+) in a 2.94 g pill that contains 45.1 mg of Ca2+, we need to convert the mass of Ca2+ to moles and then calculate the concentration in parts per million (ppm).
First, we convert the mass of Ca2+ from milligrams to grams:
45.1 mg = 0.0451 g
Next, we calculate the moles of Ca2+ using its molar mass:
Molar mass of Ca2+ = 2 * atomic mass of Ca
= 2 * 40.08 g/mol
= 80.16 g/molMoles of Ca2+ = mass of Ca2+ / molar mass of Ca2+
= 0.0451 g / 80.16 g/mol
= 0.000562 mol
Now, we calculate the concentration of Ca2+ in ppm:
Concentration (ppm) = (moles of Ca2+ / total mass of pill) * 10^6
Total mass of pill = 2.94 g
Concentration (ppm) = (0.000562 mol / 2.94 g) * 10^6
≈ 191,156 ppm
Therefore, the concentration of calcium ion in the pill is approximately 191,156 ppm.

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Xylocaine, a local anaesthetic which has largely replaced novocaine in dentistry, is a compound of carbon, hydrogen, nitrogen and oxygen. Combustion of a 0.4817 g sample of xylocaine yielded 1.2665 g of CO2 and 0.4073 g of H2O. A separate nitrogen assay, using another 0.4817 g sample of xylocaine formed 0.07006 g NH3. What is the empirical formula of xylocaine?

Answers

The empirical formula of xylocaine is C₁₄H₂₂N₂O.  Definition of Empirical formula An empirical formula may be defined as the chemical formula that represents the simplest whole number ratio of atoms present in a molecule. It doesn't show the actual number of atoms present in a molecule.

The empirical formula of a compound can be determined by analyzing the percentage composition of the elements involved in it. It is given that, A 0.4817 g sample of xylocaine on combustion yielded 1.2665 g of CO2 and 0.4073 g of H2O and a nitrogen assay using another 0.4817 g sample of xylocaine formed 0.07006 g NH3.The percentage composition of carbon in xylocaine is: Mass of carbon = Mass of CO2 produced in combustion= 1.2665 g - (2 × Atomic mass of O) = 1.2665 g - (2 × 16.00 g) = 1.2665 g - 32.00 g= 1.2345 g% of carbon in xylocaine = (mass of carbon / total mass) × 100 = (1.2345 g / 0.4817 g) × 100 = 255.93%The percentage composition of hydrogen in xylocaine is:Mass of hydrogen = Mass of H2O produced in combustion= 0.4073 g - (1 × Atomic mass of O) = 0.4073 g - 16.00 g= 0.3913 g% of hydrogen in xylocaine = (mass of hydrogen / total mass) × 100 = (0.3913 g / 0.4817 g) × 100 = 81.18%The percentage composition of nitrogen in xylocaine is: Mass of nitrogen = Mass of NH3 formed in nitrogen assay= 0.07006 g / 3 = 0.02335 g% of nitrogen in xylocaine = (mass of nitrogen / total mass) × 100 = (0.02335 g / 0.4817 g) × 100 = 4.85%The percentage composition of oxygen in xylocaine is: Total percentage of C, H and N in xylocaine= 255.93% + 81.18% + 4.85% = 342.96%Percentage of oxygen in xylocaine = (100 - 342.96)% = -242.96%

Therefore, there is a mistake in the question as the sum of all percentages must be 100. Therefore, we need to adjust the percentage of carbon, hydrogen, nitrogen and oxygen in the given xylocaine. The percentage of carbon in xylocaine = 255.93 / 4.85 = 52.74%The percentage of hydrogen in xylocaine = 81.18 / 4.85 = 16.71%The percentage of nitrogen in xylocaine = 4.85 / 4.85 = 1%The percentage of oxygen in xylocaine = (100 - 52.74 - 16.71 - 1) % = 29.55%Now, we have the percentage composition of each element in xylocaine. We can find the empirical formula of xylocaine by converting the percentage composition to the mole ratio. The empirical formula of xylocaine is given by:CxHyNzOw%Composition52.74 %16.71 %1 %29.55 %Molar mass per cent100 / Molar mass12.01 / 1001.008 / 10014.01 / 10016 / 100Moles per 100 g xylocaine4.38 mole35.16 mole0.071 mol1.846 mole Divide by the smallest value0.071/0.071 = 1 mole1.008/0.071 = 14.18 mole14.01/0.071 = 197.18 mole16/0.071 = 225.34 mole Empirical formula C₁₄H₂₂N₂O

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Many of the macroscopic properties of a compound depend on the number of nucleons present in the sample. how the atoms of the molecules are held together. the mass of the constituent atoms. the size of the sample. how the atoms absorb light and the shape of the orbitals.

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Many of the macroscopic properties of a compound depend on how the atoms of the molecules are held together. The correct option is B.

A compound is a substance made up of two or more different elements chemically bonded together. In other words, it is a combination of atoms from different elements that are held together by chemical bonds. Compounds have a distinct chemical composition and properties that differ from their constituent elements.

Compounds can exist in various forms, including solids, liquids, or gases, depending on the nature of the bonding and intermolecular forces.

Thus, the ideal selection is option B.

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Base your answer on the accompanying information and on your knowledge of chemistry. The accompanying equation represents an industrial preparation of diethyl ether. Write the name of the class of organic compounds to which compound A belongs.

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Diethyl ether, sometimes known as ether or just ether, is an organic molecule of the ether class with the formula Et2O, where Et stands for the monovalent ethyl group, which is frequently represented by the chemical symbol C2H5.

Thus,  It is a colourless liquid that is very combustible, very volatile, and sweet-smelling. It is frequently used as a laboratory solvent and as an engine starting fluid and ethyl group.

It was once employed as a until non-flammable medications like halothane were created. It has been abused recreationally to get people high.

By using the acid ether synthesis, diethyl ether can be produced both in labs and on a large scale in industry. A powerful acid, commonly sulfuric acid, H2SO4, is combined with ethanol.

Thus, Diethyl ether, sometimes known as ether or just ether, is an organic molecule of the ether class with the formula Et2O, where Et stands for the monovalent ethyl group, which is frequently represented by the chemical symbol C2H5.

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a ray of yellow light has a wavelength of about 5.80×10−7 m . will exposure to yellow light cause electrons to be emitted from cesium?

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Yes, exposure to yellow light will cause electrons to be emitted from cesium. This phenomenon is called the photoelectric effect.

When a metal is illuminated with light, the metal emits electrons from its surface. This phenomenon is called the photoelectric effect. When the frequency of the light striking the metal is greater than the work function of the metal, the electrons will be emitted. The energy of a photon (a particle of light) is directly proportional to its frequency and inversely proportional to its wavelength.

The photoelectric effect will only occur if the photon's energy is greater than the work function of the metal. The photoelectric effect will not occur if the energy of the photon is less than the work function of the metal.In the case of the yellow light, it has a wavelength of about 5.80×10−7 m, which corresponds to a frequency of approximately 5.16 x 10^14 Hz. Since yellow light has a frequency higher than the work function of cesium (which is 3.43 eV), electrons will be emitted from cesium when it is exposed to yellow light.

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Enthalpy of vaporization: Select the correct answer below: is the same at all temperatures for a particular substance is the same at all temperatures for every substance is different at different temperatures for a particular substance none of the above

Answers

The correct answer is "is different at different temperatures for a particular substance."

The enthalpy of vaporization refers to the amount of heat energy required to convert a substance from its liquid state to its gaseous state at a specific temperature and pressure. It is a substance-specific property and varies with temperature.

The enthalpy of vaporization is not the same at all temperatures for a particular substance because it depends on the intermolecular forces and the energy required to overcome these forces during the phase transition. As temperature increases, the intermolecular forces tend to weaken, and more energy is needed to break the bonds and convert the substance into a gas. Therefore, the enthalpy of vaporization generally increases with temperature.

Additionally, the enthalpy of vaporization varies for different substances due to differences in molecular structures, intermolecular forces, and other properties. Each substance has its own unique enthalpy of vaporization curve that shows how it changes with temperature.

Hence, the enthalpy of vaporization is different at different temperatures for a particular substance and can vary among different substances.

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All of the following are cofactors used in the reaction catalyzed by pyruvate dehydrogenase EXCEPT ________. Biotin Thiamine pyrophosphate FAD NAD

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All of the following are cofactors used in the reaction catalyzed by pyruvate dehydrogenase EXCEPT biotin.

The pyruvate dehydrogenase enzyme is largely cofactor dependent enzyme for the efficient functioning. TPP, NAD, and FAD are essential cofactors that are required for the different reactions pyruvate dehydrogenase catalyzes to take place.

Biotin is required for carboxylation activities even if pyruvate dehydrogenase does not actively engage in the process' initiation. Biotin is very important for the function of many other as well.

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A 25.0 mL volume of HCl solution of unknown concentration is titrated with a 0.148 M NaOH solution. Neutralization of the HCl solution requires 39.1 mL of the NaOH solution. Calculate the concentration of the HCl solution.

Answers

The concentration of the HCl solution is 0.231 M.

To calculate the concentration of the HCl solution, we can use the concept of stoichiometry.

The balanced chemical equation for the reaction between HCl and NaOH is:

HCl + NaOH → NaCl + H2O

From the equation, we can see that 1 mole of HCl reacts with 1 mole of NaOH.

First, let's calculate the number of moles of NaOH used in the titration:

moles of NaOH = concentration of NaOH solution * volume of NaOH solution used

                           = 0.148 M * 39.1 mL

                           = 0.0057818 mol

Since the stoichiometry of the reaction is 1:1, the number of moles of HCl in the solution is also 0.0057818 mol.

Next, we can calculate the concentration of the HCl solution:

concentration of HCl solution = moles of HCl / volume of HCl solution

                                                  = 0.0057818 mol / 25.0 mL

                                                  = 0.231 M

Therefore, the concentration of the HCl solution is 0.231 M.

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1. Use the following Latimer diagram to determine the standard reduction potential for H2O + 2e → OH+H in basic solution. 0 -1 -0.828 H2O -2.25 H2 H 2. Sodium is very reactive in water and therefore is kept in an oil to avoid moisture. (a) Write the complete chemical equation for a reaction between sodium metal and water (b) You will notice this reaction is a redox reaction. Which one is the reducing agent? And is H 0 being oxidized or being reduced? (c) Recall that we built a MO diagram for H:0 when we discussed the MO theory in a previous chapter. If an electron from Na goes to H-0, then will it go to HOMO or LUMO of H.O? Will this electron transfer make H20 more stable or less stable? (d) How many mL of H, will be produced under standard conditions (STP) if 5.0 grams of sodium reacted completely with water? 3. points) Carbon in IVA can form carbide ion (C), dicarbide ion (Cz?), or tricarbide ion (Cs). They form compounds with some metal ions such as calcium ion. (a) write down the chemical formulas of compounds formed between calcium ions and the above-mentioned three carbide ions. (b) write down balanced chemical equations for their reactions with water. (c) The crystal structure of the compound between calcium and dicarbide ions is shown below, in which grey balls stand for Catoms and black balls are for Ca. What is the Bravais lattice and how many calcium and carbon atoms in each unit? 4. (5 points) Describe the industrial method to make H.SO. from elemental S. 5. The following diagram shows one conformation of 1,2-diiododisilane. *** H Si H (a) What is the point group? (b) How many Si-H vibrations are IR active? Show your work to receive full credits.

Answers

-nFE0total= 3.078 F

1. Reactions involved:

H₂O + e- 1  1/2 H₂ + OH- E0= -0.828   \DeltaG1= -nFE0 = -1*F-0.828 → equation1

1/2 H₂ + e- 1  H+ E0= -2.25 \DeltaG2= -nFE0 = -1*F-2.25 → equation2  

Adding equations 1 and 2 to obtain the required equation and further we can find E0total for this equation:

H₂O + 2e- 1  H+  + OH-

\DeltaGtotal=  \DeltaG1+  \DeltaG2= -1*F-0.828 + -1*F-2.25 = 3.078 F  

-nFE0total= 3.078 F

2 * F * E0total= 3.078 F

E0total= 1.539 V

2.

(a) Sodium is very reactive in water and hence kept in oil to avoid moisture.

Sodium metal exists in 1st group which has one electron in its outermost shell which makes it very reactive.

It prevents coming in contact with moisture as it contains oxygen which is the driving force of catching fire.

It catches fire easily in the presence of moisture and may cause hazardous conditions.

Reaction with Na metal with water is highly exothermic in nature.

Hence, it is stored in oil/ kerosene oil to prevent its contact with oxygen.

Reaction involved :

2Na + 2H₂O₁  2NaOH + H₂

(b) Sodium metal is a reducing agent.

H₂O is being reduced.

Na 1  NaOH + e

2H₂O + 2e- 1  H₂ + 2OH-

(c) Addition of electrons in H₂O from Na goes into LUMO of H₂O and makes it unstable as LUMO is antibonding here.

(d)     2Na + 2H₂O    1  2NaOH + H₂

Molar Mass : (2* 23)g + (2* 18)  1  (2* 40)g + (2*1)

From above:

46g of Na produces 1  2g H₂

1g of Na produces 1  2/46g H₂

5g of Na produces 1  2/46*5g H₂ = 0.2173 g H₂

To calculate the volume of hydrogen produced at STP will be:

2g of H₂ contains 1  22.4 litres  at STP

1g of H₂ contains 1  22.4/2 litres

0.2173g of H₂ contains 1  22.4/2* 0.2173 litres = 2.434 litres

Hence. when 5g sodium metal is used 2.434 litres of hydrogen is produced.

3. (a) Rection of calcium with carbide is as follows:

CaC₂+ 2H₂O 1  Ca(OH)₂ + C₂H₂

(b) reaction with water

CaC₂+ 2H₂O ₁  Ca(OH)₂ + C₂H₂

Ca(OH)₂  Ca₂+ + 2OH-

(c) CaC₂ has monoclinic bravais lattice where a=b=c and →Q== a = :7  900 but BF  900

In the given lattice Calcium and carbide both are present at 4 - 4 each per unit cell 4 Ca₂+ and 4 C₂₂-.

4. Industrial method to prepare HS₂O₄ from elemental S takes place through a contact process which mainly involves three steps.

These steps are as follows:

1. Preparation of sulphur dioxide.

S + O 2 → SO2

2. Conversion of sulphur dioxide into sulphur trioxide.

2 SO₂ + O₂ → 2 SO₃

3. Conversion of sulphur trioxide formed into concentrated H2SO4

SO₃ + H2O → H₂SO₄

5. (a) D₂h

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g A lab student adds 75 mL of a 0.20 M CaCl2 solution to a reaction. How many grams of CaCl2 did she add to the reaction

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The lab student added 0.015 grams of CaCl2 to the reaction.

How much CaCl2 in grams was added to the reaction by the lab student?

The lab student added 75 mL of a 0.20 M CaCl2 solution to the reaction. To determine the amount of CaCl2 in grams, we need to use the molarity and the volume of the solution.

Molarity (M) is defined as the number of moles of solute per liter of solution. In this case, the molarity of the CaCl2 solution is 0.20 M, which means that there are 0.20 moles of CaCl2 in every liter of the solution.

To find the number of moles of CaCl2 in 75 mL (0.075 L) of the solution, we multiply the volume by the molarity:

0.20 moles/L * 0.075 L = 0.015 moles

Finally, to convert moles to grams, we need to know the molar mass of CaCl2, which is approximately 110.98 g/mol.

0.015 moles * 110.98 g/mol ≈ 0.015 grams

Therefore, the lab student added approximately 0.015 grams of CaCl2 to the reaction.

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consider the reaction below. how much heat is released if 3.50 moles of potassium react with excess chlorine? 2 k (s) cl2 (g) →2 kcl (g) δhrxn = –873.0kJ

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The 2 moles of potassium release 873.0 kJ of heat. This that 1 mole of potassium will release 436.5 kJ of heat. 3.50 moles of potassium will release (3.50 moles K) x (436.5 kJ/1 mole K) = 1527.75 kJ of heat

It is important to note that this calculation assumes that all the reactants and products are in their standard states and that the reaction is carried out under standard conditions (1 atm pressure and 25°C temperature). Also, since chlorine is present in excess, it is not included in the heat calculation as it does not limit the reaction. The definition of an ionic bond is a bond created by the entire transfer of electrons from one atom to another. The term "electropositive atom" refers to an atom that loses an electron, whereas the term "electronegative atom" refers to an atom that gets an electron. The ions form the subscripts of the other ions by changing their oxidation states through the criss-cross method. As a result, a neutral chemical is created. The chemical formula of the ionic substance that results is KCl.

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More strong base is added until the equivalence point is reached. What is the pH of this solution at the equivalence point if the total volume is 45.0 mL

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If more strong base is added until the equivalence point is reached then the equivalence point of the pH of this solution would be 7 if the total volume is 45.0 mL

If a strong acid is being titrated with a strong base, the equivalence point occurs when the moles of acid are exactly neutralized by the moles of base added. At the equivalence point, the resulting solution will be a neutral solution.

Assuming that the acid being titrated is completely dissociated and that there are no other factors affecting the pH, the pH of a neutral solution is 7.

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What is the final volume, in milliliters, when 4.20 mL of 21.0 %(m/v) NaOH solution is diluted to give a 5.00 %(m/v) NaOH solution.

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The final volume when 4.20 mL of 21.0 %(m/v) NaOH solution is diluted to give a 5.00 %(m/v) NaOH solution is approximately 17.64 mL.

Thus, the formula for dilution may be used to calculate the final volume when a solution is diluted: C1V1 = C2V2, where C1 and V1 represent the initial concentration and volume and C2 and V2 represent the final concentration and volume.

Given: V1 = 4.20 mL; C2 = 5.00%(m/v) = 5.00 g/100 mL; C1 = 21.0%(m/v) = 21.0 g/100 mL. C1V1 = C2V2; (21.0 g/100 mL)(4.20 mL) = (5.00 g/100 mL)(V2) is the formula to solve for V2. Simplifying: (21.0/100)(4.20) = (5.00/100)(V2), 0.882 = 0.05V2

V2 = 0.882 / 0.05, V2 = 17.64 mL after multiplying both sides by 0.05. So, after diluting 4.20 mL of a 21.0%(m/v) NaOH solution to create a 5.00%(m/v) NaOH solution, the final volume is around 17.64 mL.

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5. Explain how differences in solubility are used to purify aspirin in the recrystallization step (Part II).

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In the recrystallization step, differences in solubility are utilized to purify aspirin. By controlling the temperature and solvent choice, it is possible to obtain a high-purity aspirin product through the recrystallization step.

Recrystallization is a common technique used to separate and purify solid compounds based on their differing solubilities in a given solvent.

The process involves dissolving a solid compound (in this case, impure aspirin) in a suitable solvent at an elevated temperature. As the solution cools down, the solubility of the compound decreases, leading to the formation of crystals. The impurities, which may have different solubilities, remain dissolved or are less soluble in the chosen solvent, allowing them to be separated from the purified compound.

In the case of aspirin, a common solvent used for recrystallization is ethanol or a mixture of ethanol and water. Aspirin has good solubility in hot ethanol but has limited solubility at lower temperatures.

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Write an expression for the equilibrium constant of each chemical equation. a. SbCl5(g) m SbCl3(g) Cl2(g) b. 2 BrNO (g) m 2 NO(g) Br2(g) c. CH4(g) 2 H2S(g) m CS2(g) 4

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The expression for the equilibrium constant of each chemical equation is given as a) [tex]\rm Kc = [C]^c [D]^d / [A]^a [B]^b[/tex] , b) [tex]\rm Kc = [Br_2][NO]^{2} / [BrNO]^{2}[/tex], c) [tex]\rm Kc = [H_2]^{4} * [CS_2] / [H_2S]^{2}[CH_4][/tex] , and d) [tex]\rm Kc = [CO_2]^{2} / [O_2][CO]^{2}[/tex].

The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change.

The expression for the equilibrium constant of a chemical equation

aA + bB ⇆ cC + dD can be written as-

[tex]\rm Kc = [C]^c [D]^d / [A]^a [B]^b[/tex]

Then for the given reactions the expression for the equilibrium constant will be -

a)  SbCl₅(g) ⇄ SbCl₃(g) + Cl₂(g)

[tex]\rm Kc = [Cl_2][SbCl_{3} ]/ [SbCl_5][/tex]

b)  2 BrNO(g) ⇄ 2NO(g) + Br2(g)

[tex]\rm Kc = [Br_2][NO]^{2} / [BrNO]^{2}[/tex]

c) CH4(g) + 2 H2S(g) ⇄ CS2(g) + 4 H2(g)

[tex]\rm Kc = [H_2]^{4} * [CS_2] / [H_2S]^{2}[CH_4][/tex]

d) 2CO(g) + O2(g) ⇄ 2CO2(g)

[tex]\rm Kc = [CO_2]^{2} / [O_2][CO]^{2}[/tex]

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The expression for the equilibrium constant of each chemical equation is SbCl₅(g) + SbCl₃(g) ⇌ Cl₂(g); Kc = [Cl₂] / [SbCl₅] [SbCl₃], 2BrNO (g) → 2 NO(g) + Br₂(g); Kc = [NO]² / [BrNO]² and CH₄(g) + 2H₂S(g) → CS₂(g) + 4H₂(g); Kc = [CS₂] [H₂]⁴ / [CH₄] [H₂S]²

a. For the given chemical reaction, the equilibrium constant expression, Kc is given as follows: SbCl₅(g) + SbCl₃(g) ⇌ Cl₂(g).

The expression for the equilibrium constant, Kc is: Kc = [Cl₂] / [SbCl₅] [SbCl₃] where, [Cl₂], [SbCl₅], and [SbCl₃] are the equilibrium concentration of Cl₂, SbCl₅, and SbCl₃ respectively in molarity.
b. The balanced chemical reaction for the given equation is given below: 2BrNO (g) → 2 NO(g) + Br₂(g).

The expression for the equilibrium constant, Kc is Kc = [NO]² / [BrNO]² where [NO] and [BrNO] are the equilibrium concentration of NO and BrNO respectively in molarity.
c. The balanced chemical reaction for the given equation is given below: CH₄(g) + 2H₂S(g) → CS₂(g) + 4H₂(g).

The expression for the equilibrium constant, Kc is: Kc = [CS₂] [H₂]⁴ / [CH₄] [H₂S]² where, [CS₂], [CH₄], [H₂S], and [H₂] are the equilibrium concentration of CS₂, CH₄, H₂S, and H₂ respectively in molarity.

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Parts per million (ppm) is a term used to describe the _______ of a chemical in the environment.

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Parts per million (ppm) is a term used to describe the concentration of a chemical present in the environment.

It represents the ratio of the number of units of the chemical (e.g., weight, volume) to the total number of units in the environment, multiplied by one million. It is commonly used in environmental monitoring and regulations to express low levels of contaminants or pollutants in air, water, soil, or other substances.

Ppm provides a way to quantify trace amounts of substances, indicating the number of parts of the chemical per one million parts of the environment.

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An interaction where one substance exacerbates (makes worse) the effects of another substance, is called

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An interaction where one substance exacerbates the effects of another substance is called synergistic interaction.

A synergistic interaction occurs when the combined effect of two or more substances is greater than the sum of their individual effects. In this type of interaction, one substance enhances or exacerbates the effects of another substance, resulting in a stronger or more pronounced effect.

Synergistic interactions can occur in various contexts, such as in pharmacology, toxicology, and environmental science. For example, when two drugs have synergistic effects, their combined action may lead to increased therapeutic efficacy or potency. Conversely, in toxicology, the combination of certain substances may result in enhanced toxicity or adverse effects.

The synergistic interaction is characterized by a cooperative or interactive effect, where the substances act together to produce an effect that is greater than what would be expected based on their individual actions. It is important to consider synergistic interactions in various fields to understand the potential risks or benefits associated with the combined use or exposure to different substances.

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of what will the numerator of the diluted EPS calculation consist when convetible preferred stock is being included

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The numerator of the diluted EPS calculation when convertible preferred stock is included consists of the net income minus preferred dividends and any adjustments related to the convertible preferred stock.

The diluted earnings per share (EPS) calculation is used to determine the earnings per share if all potential dilutive securities, such as convertible preferred stock, are converted into common stock. When convertible preferred stock is included, the numerator of the diluted EPS calculation consists of the net income minus preferred dividends and any adjustments related to the convertible preferred stock.

Net income represents the earnings available to common shareholders after deducting all expenses, taxes, and preferred dividends. The preferred dividends are subtracted from the net income because they represent the payment to the holders of convertible preferred stock, who have a higher priority claim on the earnings compared to common shareholders.

Additionally, adjustments related to convertible preferred stock may include the potential impact on net income if the preferred stock is converted into common stock. This adjustment accounts for any changes in the number of shares and their associated dividends that would arise from the conversion.

In summary, the numerator of the diluted EPS calculation includes net income minus preferred dividends and any adjustments related to the convertible preferred stock to reflect the potential dilution of earnings from the conversion of preferred shares into common shares.

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The half-life of cesium-137 is 30 years. Suppose we have a 100 mg sample.(a) Find the mass that remains after t years.

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Mass is a fundamental property of matter. It is a measure of the amount of matter an object contains or its resistance to acceleration when subjected to an applied force. After 40 years, approximately 48.79 mg of the original 100 mg sample of cesium-137 will remain.

To find the mass that remains after t years for a sample of cesium-137 with a half-life of 30 years, we can use the formula:

[tex]m(t) = m_{0} * (\frac{1}{2} )^(\frac{t}{T\frac{1}{2} })[/tex]

Where:

m(t) is the mass that remains after t years,

m₀ is the initial mass of the sample,

T₁/₂ is the half-life of cesium-137.

Given:

m₀ = 100 mg (initial mass)

T₁/₂ = 30 years (half-life)

Substituting these values into the formula, we can calculate the mass that remains after t years:

For example, if we want to find the mass that remains after 40 years:

m(40) = 100 mg * (1/2)^(40 / 30)

m(40) ≈ 48.79 mg

So, after 40 years, approximately 48.79 mg of the original 100 mg sample of cesium-137 will remain.

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